歐(ou)盟于2015年6月(yue)4日在其官方刊物(wu)( Official Journal of the European Union)上發布針對(dui)RoHS 2.0 (2011/65/EU) 的修(xiu)改(gai)(gai)指令(ling)((EU)2015/865))，該修(xiu)改(gai)(gai)指令(ling)新增4項限制物(wu)質(zhi)鄰(lin)(lin)苯(ben)二(er)(er)甲酸二(er)(er)(2-乙基(ji)己)酯(zhi)(DEHP)、鄰(lin)(lin)苯(ben)二(er)(er)甲酸二(er)(er)丁酯(zhi)(DBP)、鄰(lin)(lin)苯(ben)二(er)(er)甲酸苯(ben)基(ji)丁基(ji)酯(zhi)(BBP)及鄰(lin)(lin)苯(ben)二(er)(er)甲酸二(er)(er)異(yi)丁酯(zhi)(DIBP)，限值濃度均(jun)為0.1%(基(ji)于均(jun)質(zhi)材料(liao))，并要求(qiu)其成員國在2016年12月(yue)31日前將指令(ling)轉化為本國法(fa)規(gui)，于2019年7月(yue)22日開始(shi)實(shi)施。

　　與(yu)任(ren)何有(you)(you)害(hai)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)限(xian)制(zhi)(zhi)法(fa)(fa)(fa)規的(de)(de)(de)(de)(de)(de)出臺一(yi)樣(yang)，該(gai)修改指令(ling)(ling)對(dui)(dui)(dui)(dui)(dui)相(xiang)關(guan)企業、政府管(guan)理(li)部門、標準(zhun)制(zhi)(zhi)定機(ji)(ji)(ji)構(gou)(gou)、檢(jian)測認證機(ji)(ji)(ji)構(gou)(gou)等(deng)都有(you)(you)不(bu)同程度的(de)(de)(de)(de)(de)(de)影(ying)響。一(yi)些影(ying)響是(shi)直接(jie)的(de)(de)(de)(de)(de)(de)，一(yi)些影(ying)響則是(shi)間(jian)接(jie)的(de)(de)(de)(de)(de)(de)，影(ying)響程度與(yu)之前(qian)是(shi)否開展RoHS2.0的(de)(de)(de)(de)(de)(de)應(ying)(ying)對(dui)(dui)(dui)(dui)(dui)，是(shi)否開展歐盟化(hua)學(xue)品(pin)法(fa)(fa)(fa)規(REACH)的(de)(de)(de)(de)(de)(de)應(ying)(ying)對(dui)(dui)(dui)(dui)(dui)，以及應(ying)(ying)對(dui)(dui)(dui)(dui)(dui)工作的(de)(de)(de)(de)(de)(de)深淺(qian)有(you)(you)較大(da)關(guan)聯(lian)。此次新(xin)(xin)增的(de)(de)(de)(de)(de)(de)4項(xiang)受限(xian)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)主(zhu)要用(yong)作為(wei)(wei)增塑劑或軟化(hua)劑，這些新(xin)(xin)增物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)并非(fei)一(yi)夜(ye)間(jian)提出來的(de)(de)(de)(de)(de)(de)，由(you)于(yu)RoHS 2.0(2011/65/EU)中(zhong)(zhong)提到了4種(zhong)需特別關(guan)注(zhu)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)：六溴環十二(er)烷(HBCD)、鄰(lin)苯(ben)二(er)甲酸二(er)(2-乙(yi)基己)酯(DEHP)、鄰(lin)苯(ben)二(er)甲酸二(er)丁酯(DBP)及鄰(lin)苯(ben)二(er)甲酸苯(ben)基丁基酯(BBP)，其中(zhong)(zhong)的(de)(de)(de)(de)(de)(de)3種(zhong)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)是(shi)此次新(xin)(xin)增物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)，而無(wu)論是(shi)修訂指令(ling)(ling)中(zhong)(zhong)新(xin)(xin)增的(de)(de)(de)(de)(de)(de)受控(kong)(kong)(kong)(kong)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)，還是(shi)RoHS 2.0中(zhong)(zhong)的(de)(de)(de)(de)(de)(de)關(guan)注(zhu)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)，都屬(shu)于(yu)REACH中(zhong)(zhong)的(de)(de)(de)(de)(de)(de)高關(guan)注(zhu)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)，此外，DEHP, BBP和DBP在(zai)REACH中(zhong)(zhong)之前(qian)就已被列(lie)(lie)為(wei)(wei)在(zai)玩具(ju)產(chan)(chan)品(pin)中(zhong)(zhong)限(xian)制(zhi)(zhi)使用(yong)，因而對(dui)(dui)(dui)(dui)(dui)于(yu)長期(qi)有(you)(you)效開展出口歐盟相(xiang)關(guan)產(chan)(chan)品(pin)有(you)(you)害(hai)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)管(guan)控(kong)(kong)(kong)(kong)的(de)(de)(de)(de)(de)(de)機(ji)(ji)(ji)構(gou)(gou)而言，實(shi)際(ji)上不(bu)同程度對(dui)(dui)(dui)(dui)(dui)新(xin)(xin)增的(de)(de)(de)(de)(de)(de)4種(zhong)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)之前(qian)就有(you)(you)所(suo)管(guan)控(kong)(kong)(kong)(kong)。當然，列(lie)(lie)為(wei)(wei)關(guan)注(zhu)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)與(yu)列(lie)(lie)為(wei)(wei)限(xian)制(zhi)(zhi)使用(yong)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)(基于(yu)均質(zhi)(zhi)(zhi)(zhi)(zhi)材(cai)料(liao))間(jian)的(de)(de)(de)(de)(de)(de)區(qu)別是(shi)很大(da)的(de)(de)(de)(de)(de)(de)，各機(ji)(ji)(ji)構(gou)(gou)在(zai)應(ying)(ying)對(dui)(dui)(dui)(dui)(dui)RoHS2.0中(zhong)(zhong)，自(zi)然針對(dui)(dui)(dui)(dui)(dui)法(fa)(fa)(fa)規中(zhong)(zhong)的(de)(de)(de)(de)(de)(de)6項(xiang)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)(鉛、鎘、汞、六價鉻、PBBs、PBDEs)會嚴加(jia)管(guan)控(kong)(kong)(kong)(kong)，而對(dui)(dui)(dui)(dui)(dui)于(yu)關(guan)注(zhu)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)，有(you)(you)的(de)(de)(de)(de)(de)(de)機(ji)(ji)(ji)構(gou)(gou)采取同法(fa)(fa)(fa)規中(zhong)(zhong)6項(xiang)要求一(yi)致(zhi)的(de)(de)(de)(de)(de)(de)方式管(guan)控(kong)(kong)(kong)(kong)，有(you)(you)的(de)(de)(de)(de)(de)(de)則會采取相(xiang)對(dui)(dui)(dui)(dui)(dui)寬松的(de)(de)(de)(de)(de)(de)方式比如自(zi)我申(shen)明或篩查等(deng)，有(you)(you)的(de)(de)(de)(de)(de)(de)機(ji)(ji)(ji)構(gou)(gou)則只針對(dui)(dui)(dui)(dui)(dui)法(fa)(fa)(fa)規中(zhong)(zhong)的(de)(de)(de)(de)(de)(de)6項(xiang)進行管(guan)控(kong)(kong)(kong)(kong)，不(bu)同的(de)(de)(de)(de)(de)(de)管(guan)控(kong)(kong)(kong)(kong)政策導致(zhi)新(xin)(xin)增受控(kong)(kong)(kong)(kong)物(wu)(wu)(wu)(wu)(wu)(wu)質(zhi)(zhi)(zhi)(zhi)(zhi)后的(de)(de)(de)(de)(de)(de)影(ying)響不(bu)同。

　　對(dui)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)機(ji)構(gou)(包括第一(yi)方(fang)(fang)(fang)(fang)(fang)、第二(er)(er)(er)方(fang)(fang)(fang)(fang)(fang)及第三方(fang)(fang)(fang)(fang)(fang)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi))來說，新(xin)(xin)增(zeng)分(fen)析測(ce)(ce)(ce)(ce)(ce)試項(xiang)(xiang)目(mu)(mu)則(ze)(ze)(ze)意(yi)味著要(yao)(yao)建(jian)(jian)立新(xin)(xin)的(de)(de)(de)(de)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)，若(ruo)有(you)現(xian)成的(de)(de)(de)(de)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)，則(ze)(ze)(ze)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)可(ke)通過(guo)實(shi)(shi)(shi)(shi)驗(yan)(yan)確(que)(que)認(ren)(ren)、證實(shi)(shi)(shi)(shi)現(xian)有(you)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)后(hou)建(jian)(jian)立檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)，若(ruo)無現(xian)成的(de)(de)(de)(de)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)，則(ze)(ze)(ze)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)需要(yao)(yao)參考(kao)其(qi)它標(biao)(biao)(biao)準(zhun)(zhun)(zhun)建(jian)(jian)立實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)，并(bing)經(jing)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)確(que)(que)認(ren)(ren)等(deng)工作(zuo)(zuo)后(hou)應(ying)(ying)用(yong)。一(yi)般(ban)而言，除非(fei)(fei)用(yong)于企業(ye)自檢(jian)(jian)(jian)(jian)等(deng)特定(ding)(ding)情形，還要(yao)(yao)求(qiu)相(xiang)(xiang)關(guan)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)的(de)(de)(de)(de)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)項(xiang)(xiang)目(mu)(mu)要(yao)(yao)通過(guo)ISO/IEC 17025實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)體系認(ren)(ren)可(ke)。而按(an)RoHS2.0實(shi)(shi)(shi)(shi)施中(zhong)(zhong)技術(shu)文(wen)件(EN 50581:2012 Technical documentation for the assessment of electrical and electronic products with respect to the restriction of hazardous substances)要(yao)(yao)求(qiu)，強調在(zai)提交的(de)(de)(de)(de)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)報告中(zhong)(zhong)，檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)要(yao)(yao)采用(yong)或參考(kao)EN 62321。無論那種類型的(de)(de)(de)(de)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)或管(guan)控機(ji)構(gou)，采用(yong)公(gong)認(ren)(ren)的(de)(de)(de)(de)國(guo)(guo)際(ji)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)非(fei)(fei)常重要(yao)(yao)，眾所(suo)周知(zhi)，針對(dui)原(yuan)RoHS中(zhong)(zhong)6項(xiang)(xiang)物(wu)質(zhi)(zhi)(zhi)(鉛、鎘、汞、六價(jia)鉻、PBBs、PBDEs)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)，IEC 62321(EN 62321)是公(gong)認(ren)(ren)的(de)(de)(de)(de)該(gai)行業(ye)國(guo)(guo)際(ji)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)，該(gai)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)由 IEC/TC111 WG3有(you)害物(wu)質(zhi)(zhi)(zhi)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)工作(zuo)(zuo)組(zu)牽(qian)頭制定(ding)(ding)，目(mu)(mu)前仍在(zai)不(bu)(bu)(bu)斷修(xiu)訂(ding)(ding)中(zhong)(zhong)，考(kao)慮到行業(ye)內分(fen)析測(ce)(ce)(ce)(ce)(ce)試工作(zuo)(zuo)的(de)(de)(de)(de)實(shi)(shi)(shi)(shi)際(ji)需要(yao)(yao)，修(xiu)訂(ding)(ding)的(de)(de)(de)(de)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)中(zhong)(zhong)不(bu)(bu)(bu)再(zai)只是限于檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)6種受控物(wu)質(zhi)(zhi)(zhi)(鉛、鉻、汞、六價(jia)鉻、多溴(xiu)聯苯(ben)、多溴(xiu)聯苯(ben)醚)，而是增(zeng)加(jia)了(le)其(qi)它物(wu)質(zhi)(zhi)(zhi)的(de)(de)(de)(de)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)，比如目(mu)(mu)前制修(xiu)訂(ding)(ding)的(de)(de)(de)(de)IEC 62321系列(lie)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)中(zhong)(zhong)的(de)(de)(de)(de)IEC 62321-8 Ed.1，該(gai)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)采用(yong)不(bu)(bu)(bu)同的(de)(de)(de)(de)質(zhi)(zhi)(zhi)譜(pu)(pu)(pu)聯機(ji)手段(裂解(jie)氣(qi)相(xiang)(xiang)色譜(pu)(pu)(pu)質(zhi)(zhi)(zhi)譜(pu)(pu)(pu)(Py-GC-MS)、離子附(fu)著質(zhi)(zhi)(zhi)譜(pu)(pu)(pu)(IAMS)、氣(qi)相(xiang)(xiang)色譜(pu)(pu)(pu)質(zhi)(zhi)(zhi)譜(pu)(pu)(pu)(GC-MS)、液相(xiang)(xiang)色譜(pu)(pu)(pu)質(zhi)(zhi)(zhi)譜(pu)(pu)(pu)(LC-MS))測(ce)(ce)(ce)(ce)(ce)定(ding)(ding)聚(ju)合(he)物(wu)中(zhong)(zhong)不(bu)(bu)(bu)同鄰(lin)苯(ben)化(hua)(hua)合(he)物(wu)如鄰(lin)苯(ben)二(er)(er)(er)甲(jia)(jia)酸二(er)(er)(er)異丁酯(zhi)(zhi)(zhi)(DIBP)、鄰(lin)苯(ben)二(er)(er)(er)甲(jia)(jia)酸二(er)(er)(er)正(zheng)(zheng)丁酯(zhi)(zhi)(zhi)(DBP)、鄰(lin)苯(ben)二(er)(er)(er)甲(jia)(jia)酸丁基(ji)酯(zhi)(zhi)(zhi)(BBP)、鄰(lin)苯(ben)二(er)(er)(er)甲(jia)(jia)酸(2-乙基(ji)已基(ji))酯(zhi)(zhi)(zhi)(DEHP)、鄰(lin)苯(ben)二(er)(er)(er)甲(jia)(jia)酸二(er)(er)(er)正(zheng)(zheng)辛(xin)酯(zhi)(zhi)(zhi)(DNOP)、鄰(lin)苯(ben)二(er)(er)(er)甲(jia)(jia)酸二(er)(er)(er)異壬(ren)酯(zhi)(zhi)(zhi)(DINP)、鄰(lin)苯(ben)二(er)(er)(er)甲(jia)(jia)酸二(er)(er)(er)異葵酯(zhi)(zhi)(zhi)(DIDP)等(deng)，其(qi)中(zhong)(zhong)包含了(le)RoHS2.0修(xiu)訂(ding)(ding)指令中(zhong)(zhong)新(xin)(xin)增(zeng)的(de)(de)(de)(de)4項(xiang)(xiang)物(wu)質(zhi)(zhi)(zhi) DEHP、DBP、BBP以及DIBP (IEC 62321-8 Ed.1.0 Determination of certain substances in electrotechnical products –Part 8: Determination of each phthalate in polymer materials by Pyrolyzer Gas Chromatography-Mass Spectrometry (Py-GC-MS), Ion Attachment Mass Spectrometry (IAMS), Gas Chromatography-Mass Spectrometry (GC-MS) and Liquid Chromatography – Mass Spectrometry (LC-MS))，此也為各(ge)機(ji)構(gou)對(dui)新(xin)(xin)增(zeng)4項(xiang)(xiang)物(wu)質(zhi)(zhi)(zhi)的(de)(de)(de)(de)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)應(ying)(ying)對(dui)在(zai)管(guan)控上確(que)(que)立了(le)方(fang)(fang)(fang)(fang)(fang)向，但該(gai)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)目(mu)(mu)前尚(shang)未正(zheng)(zheng)式(shi)發布，計劃正(zheng)(zheng)式(shi)發布時間為2016年。該(gai)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)出(chu)(chu)臺(tai)(tai)前，相(xiang)(xiang)關(guan)項(xiang)(xiang)目(mu)(mu)通過(guo)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)認(ren)(ren)可(ke)的(de)(de)(de)(de)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)可(ke)以有(you)效(xiao)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)新(xin)(xin)增(zeng)的(de)(de)(de)(de)幾個化(hua)(hua)合(he)物(wu)，標(biao)(biao)(biao)準(zhun)(zhun)(zhun)出(chu)(chu)臺(tai)(tai)后(hou)，則(ze)(ze)(ze)原(yuan)則(ze)(ze)(ze)上所(suo)有(you)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)都要(yao)(yao)執行IEC 62321，并(bing)通過(guo)相(xiang)(xiang)關(guan)ISO/IEC17025實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)認(ren)(ren)可(ke)。對(dui)于已通過(guo)該(gai)項(xiang)(xiang)目(mu)(mu)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)認(ren)(ren)可(ke)的(de)(de)(de)(de)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)，需要(yao)(yao)將現(xian)有(you)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)轉化(hua)(hua)為新(xin)(xin)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)并(bing)通過(guo)認(ren)(ren)可(ke)，對(dui)之前未開展相(xiang)(xiang)關(guan)檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)的(de)(de)(de)(de)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)，則(ze)(ze)(ze)不(bu)(bu)(bu)僅需要(yao)(yao)按(an)新(xin)(xin)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)建(jian)(jian)立檢(jian)(jian)(jian)(jian)測(ce)(ce)(ce)(ce)(ce)方(fang)(fang)(fang)(fang)(fang)法(fa)(fa)，還需要(yao)(yao)完(wan)成能(neng)力驗(yan)(yan)證、不(bu)(bu)(bu)確(que)(que)定(ding)(ding)度評估(gu)等(deng)工作(zuo)(zuo)為通過(guo)實(shi)(shi)(shi)(shi)驗(yan)(yan)室(shi)(shi)(shi)認(ren)(ren)可(ke)打下基(ji)礎。與國(guo)(guo)際(ji)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)工作(zuo)(zuo)組(zu)(IEC/TC111 WG3)相(xiang)(xiang)對(dui)應(ying)(ying)，國(guo)(guo)內的(de)(de)(de)(de)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)化(hua)(hua)技術(shu)委員會(hui)(TC297)也正(zheng)(zheng)密(mi)切跟蹤(zong)國(guo)(guo)際(ji)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)的(de)(de)(de)(de)制定(ding)(ding)，相(xiang)(xiang)應(ying)(ying)的(de)(de)(de)(de)國(guo)(guo)內轉化(hua)(hua)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)一(yi)般(ban)也會(hui)隨國(guo)(guo)際(ji)標(biao)(biao)(biao)準(zhun)(zhun)(zhun)出(chu)(chu)臺(tai)(tai)后(hou)陸續出(chu)(chu)臺(tai)(tai)，不(bu)(bu)(bu)過(guo)按(an)以往(wang)經(jing)驗(yan)(yan)，時間上會(hui)較滯后(hou)。

　　RoHS2.0修(xiu)訂指(zhi)令的(de)(de)(de)出臺無(wu)形中加(jia)速了相(xiang)關標(biao)準的(de)(de)(de)制(zhi)定(ding)(ding)(ding)(ding)(ding)工作(zuo)，對我國正在制(zhi)修(xiu)定(ding)(ding)(ding)(ding)(ding)的(de)(de)(de)電(dian)子(zi)電(dian)氣(qi)產品污(wu)染控制(zhi)管理辦法及(ji)配(pei)套(tao)標(biao)準的(de)(de)(de)制(zhi)修(xiu)定(ding)(ding)(ding)(ding)(ding)都(dou)會(hui)產生影響。另一方(fang)(fang)面(mian)，修(xiu)訂指(zhi)令也會(hui)改(gai)變實(shi)驗(yan)室傳統的(de)(de)(de)RoHS 6項(xiang)檢(jian)(jian)測運(yun)作(zuo)模(mo)式，尤(you)其是對整(zheng)機測試，因成本等(deng)因素，之前的(de)(de)(de)6種(zhong)受(shou)(shou)控物(wu)(wu)質原則上可首先(xian)(xian)采用(yong)(yong)XRF測定(ding)(ding)(ding)(ding)(ding)鉛、鎘、汞、鉻、溴(xiu)的(de)(de)(de)總量(liang)(liang)，然(ran)后對不(bu)能確定(ding)(ding)(ding)(ding)(ding)的(de)(de)(de)部分(fen)采用(yong)(yong)化(hua)學(xue)手段(duan)(duan)(比如等(deng)離子(zi)發射光(guang)譜(ICP-OES)及(ji)氣(qi)相(xiang)色譜質譜(GC-MS))確認結果，不(bu)少(shao)企(qi)(qi)業實(shi)驗(yan)室配(pei)有(you)XRF作(zuo)為篩(shai)查工具，一些企(qi)(qi)業的(de)(de)(de)RoHS體系也強調(diao)XRF在有(you)害物(wu)(wu)質控制(zhi)中的(de)(de)(de)使用(yong)(yong)，對整(zheng)機進行(xing)(xing)(xing)RoHS有(you)害物(wu)(wu)質檢(jian)(jian)測時，一些第三(san)方(fang)(fang)實(shi)驗(yan)室也會(hui)用(yong)(yong)XRF進行(xing)(xing)(xing)RoHS初步核查，但修(xiu)改(gai)指(zhi)令中新增的(de)(de)(de)4種(zhong)化(hua)合物(wu)(wu)無(wu)法用(yong)(yong)XRF獲取有(you)用(yong)(yong)信息，只(zhi)能用(yong)(yong)各類質譜聯(lian)用(yong)(yong)手段(duan)(duan)(Py-GC-MS, IAMS, GC-MS 或(huo) LC-MS等(deng))定(ding)(ding)(ding)(ding)(ding)量(liang)(liang)或(huo)半定(ding)(ding)(ding)(ding)(ding)量(liang)(liang)測試，過(guo)去僅(jin)采用(yong)(yong)XRF篩(shai)選(xuan)的(de)(de)(de)方(fang)(fang)式已(yi)不(bu)能覆蓋所有(you)受(shou)(shou)限物(wu)(wu)質，事實(shi)上，隨著受(shou)(shou)限物(wu)(wu)質的(de)(de)(de)增加(jia)，今(jin)后必然(ran)需(xu)(xu)要采用(yong)(yong)多(duo)種(zhong)手段(duan)(duan)才能完(wan)成初步篩(shai)查任(ren)務，同過(guo)去一樣，完(wan)成受(shou)(shou)限物(wu)(wu)質的(de)(de)(de)準確定(ding)(ding)(ding)(ding)(ding)量(liang)(liang)測定(ding)(ding)(ding)(ding)(ding)需(xu)(xu)要多(duo)種(zhong)手段(duan)(duan)的(de)(de)(de)并用(yong)(yong)。相(xiang)應地，實(shi)驗(yan)室或(huo)各管控機構都(dou)需(xu)(xu)要不(bu)同程度(du)上調(diao)整(zheng)自已(yi)的(de)(de)(de)RoHS有(you)害物(wu)(wu)質檢(jian)(jian)測運(yun)行(xing)(xing)(xing)模(mo)式，XRF仍然(ran)是可行(xing)(xing)(xing)的(de)(de)(de)初篩(shai)選(xuan)工具，但只(zhi)針對原RoHS中6項(xiang)物(wu)(wu)質，故之前只(zhi)有(you)XRF的(de)(de)(de)實(shi)驗(yan)室需(xu)(xu)要考慮(lv)或(huo)者(zhe)分(fen)包項(xiang)目到第三(san)方(fang)(fang)或(huo)者(zhe)添置相(xiang)關設備建立(li)(li)方(fang)(fang)法，對已(yi)有(you)基本儀器(qi)(如XRF、ICP-OES、GC-MS)并建立(li)(li)了方(fang)(fang)法的(de)(de)(de)實(shi)驗(yan)室，考慮(lv)到樣品種(zhong)類及(ji)樣品量(liang)(liang)大小的(de)(de)(de)不(bu)同，以及(ji)檢(jian)(jian)測結果的(de)(de)(de)用(yong)(yong)途(tu)不(bu)同，不(bu)少(shao)情況下(xia)直接定(ding)(ding)(ding)(ding)(ding)量(liang)(liang)測試比先(xian)(xian)篩(shai)選(xuan)后化(hua)學(xue)測試確認更為有(you)效，實(shi)驗(yan)室需(xu)(xu)按自已(yi)的(de)(de)(de)情況調(diao)整(zheng)檢(jian)(jian)測方(fang)(fang)案。

　　作者：高志祥

　　作(zuo)者為萊茵技(ji)術(上海)有限公司資(zi)深技(ji)術經(jing)理、教授級(ji)高級(ji)工程師、國際電工產(chan)品(pin)測試與認證(IECEE)同行評(ping)審專家